Au 4f spin–orbit coupling effects in supported gold nanoparticles
Author:
Affiliation:
1. Chimie-Physique des Matériaux
2. Université Libre de Bruxelles (ULB)
3. Bruxelles
4. Belgium
5. G.V. Kurdyumov Institute for Metal Physics NASU
6. Voiland School of Chemical Engineering and Bioengineering
Abstract
We reveal that the ratio of spin–orbit components in X-ray photoelectron Au 4f spectra of titania-supported gold nanoparticles deviates from the statistical ratio 4 : 3 and demonstrates an appreciable dependence on the concentration of Au atoms on the surface of TiO2 support and size of Au nanoparticles.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03362H
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