Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying-Reference-Cited by-同舟云学术

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

Published:2017 Issue:1 Volume:53 Page:130-133
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fuhr Javier D.¹²³,van der Meijden Maarten W.⁴⁵⁶,Cristina Lucila J.¹²³,Rodríguez Luis M.¹²³,Kellogg Richard M.⁴⁵⁶,Gayone J. Esteban¹²³,Ascolani Hugo¹²³,Lingenfelder Magalí⁷⁸⁹^ORCID

Affiliation:

1. Centro Atómico Bariloche

2. Bariloche

3. Argentina

4. Syncom BV

5. 9747 AT Groningen

6. The Netherlands

7. Max Planck-EPFL Laboratory for Molecular Nanoscience

8. EPFL SB CMNT NL-CMNT

9. Switzerland

Abstract

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC06785A

Reference27 articles.

1. Stereochemical Recognition of Helicenes on Metal Surfaces

2. Zur Kenntniss der Terpene und der ätherischen Oele. Ueber gebromte Derivate der Carvonreihe

3. On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts

4. Are Racemic Crystals Favored over Homochiral Crystals by Higher Stability or by Kinetics? Insights from Comparative Studies of Crystalline Stereoisomers

5. Nanoscale insights in the creation and transfer of chirality in amino acid monolayers at defined metal surfaces

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