Palladium complexes of N-heterocyclic carbenes displaying an unsymmetricalN-alkylfluorenyl/N′-aryl substitution pattern and their behaviour in Suzuki–Miyaura cross coupling-Reference-Cited by-同舟云学术

Palladium complexes of N-heterocyclic carbenes displaying an unsymmetricalN-alkylfluorenyl/N′-aryl substitution pattern and their behaviour in Suzuki–Miyaura cross coupling

Published:2019 Issue:38 Volume:48 Page:14516-14529
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Almallah Hamzé¹²³⁴⁵,Brenner Eric¹²³⁴⁵^ORCID,Matt Dominique¹²³⁴⁵^ORCID,Harrowfield Jack⁶⁷³⁸⁵^ORCID,Jahjah Mohamad⁹¹⁰¹¹¹²¹³,Hijazi Akram⁹¹⁰¹¹¹²¹³

Affiliation:

1. Laboratoire de Chimie Inorganique Moléculaire et Catalyse

2. Institut de Chimie (UMR 7177 CNRS)

3. Université de Strasbourg

4. 67070 Strasbourg Cedex

5. France

6. Institut de Science et Ingénierie Supramoléculaires (ISIS)

7. UMR 7606 CNRS

8. 67083 Strasbourg cedex

9. Inorganic and Organometallic Coordination Chemistry Laboratory

10. Faculty of Sciences

11. Lebanese University

12. R. Hariri University Campus

13. Beyrouth

Abstract

Pd–PEPPSI complexes with a mixedN-alkylfluorenyl/N′-aryl substitution pattern were found to be considerably more active in Suzuki–Miyaura cross coupling than the standard complexes [PdCl₂(IMes)(Py)] and [PdCl₂(IPr)(Py)].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02948F

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