Enhancing the catalytic activity of Ru NPs deposited with carbon species in yolk–shell nanostructures-Reference-Cited by-同舟云学术

Enhancing the catalytic activity of Ru NPs deposited with carbon species in yolk–shell nanostructures

Published:2016 Issue:28 Volume:4 Page:10956-10963
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Guo Miao¹²³⁴⁵,Lan Guojun⁶⁷⁸⁵,Peng Juan¹²³⁴⁵,Li Mingrun¹²³⁴⁵,Yang Qihua¹²³⁴⁵,Li Can¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Catalysis

2. Dalian Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Dalian 116023

5. China

6. Institute of Industrial Catalysis

7. Zhejiang University of Technology

8. Hangzhou

Abstract

An efficient H₂ pyrolysis method was developed to remove stabilizers on metal surfaces with Ru–poly(amindoamine) as the model. Ru NPs after pyrolysis with the TOF as high as 20 300 h⁻¹ are among the most active solid catalysts for toluene hydrogenation. The high catalytic activity could be mainly attributed to the high exposure degree and accelerating effect of C and N residues at the Ru surface.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/TA/C6TA03576K

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