Bending good beats breaking bad: phase separation patterns in individual cathode particles upon lithiation and delithiation-Reference-Cited by-同舟云学术

Bending good beats breaking bad: phase separation patterns in individual cathode particles upon lithiation and delithiation

Published:2020 Issue:12 Volume:7 Page:3275-3290
ISSN:2051-6347
Container-title:Materials Horizons
language:en
Short-container-title:Mater. Horiz.

Author:

Santos David A.¹²³⁴⁵,Andrews Justin L.¹²³⁴⁵^ORCID,Bai Yang⁶⁷⁸⁹¹⁰,Stein Peter⁶⁷⁸⁹¹⁰,Luo Yuting¹²³⁴⁵,Zhang Yuwei¹¹²³⁴,Pharr Matt¹¹²³⁴,Xu Bai-Xiang⁶⁷⁸⁹¹⁰^ORCID,Banerjee Sarbajit¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. Department of Materials Science and Engineering

6. Institute of Materials Science

7. Mechanics of Functional Materials

8. Technische Universität Darmstadt

9. 64287 Darmstadt

10. Germany

11. Department of Mechanical Engineering

Abstract

This work elucidates the nature of spinodal decomposition, evidences fundamental differences in phase separation between lithiation and delithiation, and the highlights the role of chemomechanical coupling in shaping separation patterns.

Funder

National Science Foundation

Deutsche Forschungsgemeinschaft

National Aeronautics and Space Administration

Natural Sciences and Engineering Research Council of Canada

National Research Council Canada

Canadian Institutes of Health Research

Western Economic Diversification Canada

University of Saskatchewan

Publisher

Royal Society of Chemistry (RSC)

Subject