Greasy tails switch 1D-coordination [{Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)}n] polymers to discrete [Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)2] complexes-Reference-Cited by-同舟云学术

Greasy tails switch 1D-coordination [{Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)}n] polymers to discrete [Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)2] complexes

Published:2014 Issue:42 Volume:16 Page:9915-9929
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Klein Y. Maximilian¹²³,Constable Edwin C.¹²³,Housecroft Catherine E.¹²³,Zampese Jennifer A.¹²³,Crochet Aurélien⁴⁵⁶

Affiliation:

1. Department of Chemistry

2. University of Basel

3. CH4056 Basel, Switzerland

4. Department of Physics

5. University of Fribourg

6. CH-1700 Fribourg, Switzerland

Abstract

Polymers [{Zn₂(OAc)₄(4′-(4-ROC₆H₄)-4,2′:6′,4′′-tpy)}_n] with dominant π-stacking interactions are favoured for small RO groups; with long chains, there is a switch to discrete molecules.

Funder

European Research Council

Swiss National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CE/C4CE01422G

Reference40 articles.

1. 4,2′:6′,4′′-Terpyridines: diverging and diverse building blocks in coordination polymers and metallomacrocycles

2. Coordination compounds of 4,2′-6′,4″-terpyridine, [MCl2(4,2′-6′,4″-terpyridine)], M = Mn(II), Co(II), Ni(II), Cu(II) or Zn(II). Crystal structure of catena-poly [(dichlorozinc)-μ-(4,2′-6′,4″-terpyridine)]