Mechanism for formation of atmospheric Cl atom precursors in the reaction of dinitrogen oxides with HCl/Cl− on aqueous films-Reference-Cited by-同舟云学术

Mechanism for formation of atmospheric Cl atom precursors in the reaction of dinitrogen oxides with HCl/Cl− on aqueous films

Published:2015 Issue:29 Volume:17 Page:19360-19370
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Hammerich Audrey Dell¹²³⁴,Finlayson-Pitts Barbara J.¹⁵⁶⁴,Gerber R. Benny¹⁵⁶⁴⁷

Affiliation:

1. Department of Chemistry

2. University of Illinois at Chicago

3. Chicago

4. USA

5. University of California Irvine

6. Irvine

7. Institute of Chemistry and the Fritz Haber Research Center

Abstract

Formation of atmospheric chlorine atom precursors ClNO₂ and ClNO in the reaction of HCl with oxides of nitrogen on a water film: left – formation of N–Cl bond as N–O bond breaks; right – concurrent changes in Mulliken charges.

Funder

Directorate for Mathematical and Physical Sciences

Division of Chemistry

Israel Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP02664D

Reference112 articles.

1. Chlorine atoms as a potential tropospheric oxidant in the marine boundary layer

2. Physical Chemistry of Airborne Sea Salt Particles and Their Components

3. B. J. Finlayson-Pitts and J. N.Pitts, Chemistry of the Upper and Lower Atmosphere - Theory, Experiments, and Applications, Academic Press, San Diego, 2000

4. The Tropospheric Chemistry of Sea Salt: A Molecular-Level View of the Chemistry of NaCl and NaBr

5. Are chlorine atoms significant tropospheric free radicals?

Cited by 21 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Mechanistic Insights into N₂O₅-Halide Ions Chemistry at the Air–Water Interface;Journal of the American Chemical Society;2024-07-29

2. Formulation of the cosmic ray–driven electron-induced reaction mechanism for quantitative understanding of global ozone depletion;Proceedings of the National Academy of Sciences;2023-06-26

3. Weak Temperature Dependence of the Relative Rates of Chlorination and Hydrolysis of N₂O₅ in NaCl–Water Solutions;The Journal of Physical Chemistry A;2023-02-14

4. Effects of Microhydration on the Mechanisms of Hydrolysis and Cl ⁻ Substitution in Reactions of N ₂ O ₅ and Seawater;ChemPhysChem;2022-12-05

5. Reduction and Photoreduction of NO₂ in Humic Acid Films as a Source of HONO, ClNO, N₂O, NO_X, and Organic Nitrogen;ACS Earth and Space Chemistry;2022-12-01