Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors-Reference-Cited by-同舟云学术

Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors

Published:2016 Issue:41 Volume:45 Page:16190-16204
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lang Georgette M.¹²³⁴,Skaper Dirk⁵⁶⁷⁸,Hampel Frank⁵⁶⁷⁸,Gladysz John A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. Texas 77842-3012

4. USA

5. Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials

6. Friedrich-Alexander-Universität Erlangen-Nürnberg

7. 91054 Erlangen

8. Germany

Abstract

Substitution reactions of 4c⁺ BF₄⁻ afford the title complexes 9c-X, the Fe(CO)(NO)(X) moieties of which rapidly rotate within the diphosphine cage. Trends are interpreted in terms of horizontal/vertical van der Waals clearance.

Funder

Division of Chemistry

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03258C

Reference58 articles.

1. See http://www.gyroscopes.org/uses.asp

2. Molecular Gyroscopes: {Fe(CO)3} and {Fe(CO)2(NO)}+ Rotators Encased in Three-Spoke Stators; Facile Assembly by Alkene Metatheses