Abnormal NHC ruthenium catalysts: mechanistic investigations of their preparation and steric influence on catalytic performance-Reference-Cited by-同舟云学术

Abnormal NHC ruthenium catalysts: mechanistic investigations of their preparation and steric influence on catalytic performance

Published:2022 Issue:18 Volume:12 Page:5597-5603
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Böth Alexander D.¹^ORCID,Sauer Michael J.¹,Baratta Walter²^ORCID,Kühn Fritz E.¹^ORCID

Affiliation:

1. Molecular Catalysis, Department of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, 85748 Garching bei München, Germany

2. Dipartimento DI4A, Università di Udine, Via Cotonificio 108, 33100 Udine, Italy

Abstract

Preparation of bis-aNHC Ru catalysts, identification of formation intermediates and application in transfer hydrogenation and Oppenauer-type oxidation, observing an inversion in activity appearing to be dependent on steric hindrance.

Funder

Graduate School, Technische Universität München

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY01036D

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