Photochemical generation of acyl and carbamoyl radicals using a nucleophilic organic catalyst: applications and mechanism thereof-Reference-Cited by-同舟云学术

Photochemical generation of acyl and carbamoyl radicals using a nucleophilic organic catalyst: applications and mechanism thereof

Published:2020 Issue:24 Volume:11 Page:6312-6324
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

de Pedro Beato Eduardo¹²³⁴^ORCID,Mazzarella Daniele¹²³⁴^ORCID,Balletti Matteo¹²³⁴^ORCID,Melchiorre Paolo¹²³⁴⁵^ORCID

Affiliation:

1. ICIQ – Institute of Chemical Research of Catalonia

2. The Barcelona Institute of Science and Technology

3. Tarragona

4. Spain

5. ICREA

Abstract

An organic catalyst uses low-energy photons to generate acyl and carbamoyl radicals upon activation of the corresponding chlorides via a nucleophilic acyl substitution path. The synthetic potential and the mechanism of this strategy are discussed.

Funder

Ministerio de Economía y Competitividad

H2020 European Research Council

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02313B

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