Hydrothermal conversion of mixed uranium(<scp>iv</scp>)–cerium(<scp>iii</scp>) oxalates into U1−xCexO2+δ·nH2O solid solutions-Reference-Cited by-同舟云学术

Hydrothermal conversion of mixed uranium(iv)–cerium(iii) oxalates into U_1−xCe_xO_2+δ·nH₂O solid solutions

Published:2023 Issue:31 Volume:52 Page:10951-10968
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Benarib S.¹^ORCID,Dacheux N.¹^ORCID,Le Goff X. F.¹^ORCID,Lautru J.¹,Di Mascio L.¹,Clavier N.¹^ORCID

Affiliation:

1. ICSM, Univ Montpellier, CEA, CNRS, ENSCM, Marcoule, France

Abstract

Hydrothermal conversion of U(iv)–Ce(iii) oxalates allows the quantitative synthesis of morphology-tunable solid solutions of (U,Ce)O2±δ. Such a process appears to be a credible alternative route for the synthesis of MOx nuclear fuel.

Funder

Commissariat à l'Énergie Atomique et aux Énergies Alternatives

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01510F

Reference71 articles.

1. Recycling the Actinides, The Cornerstone of Any Sustainable Nuclear Fuel Cycles

2. Characterization of plutonium distribution in MIMAS MOX by image analysis

3. Characterization of un-irradiated MIMAS MOX fuel by Raman spectroscopy and EPMA

4. Actinide oxalates, solid state structures and applications

5. Crystal Growth and First Crystallographic Characterization of Mixed Uranium(IV)–Plutonium(III) Oxalates

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1. Hydrothermal conversion of cerium oxalate to CeO₂: a parade of oxalate and water coordination modes;New Journal of Chemistry;2024

2. Reductive hydrothermal conversion of uranyl oxalates into UO_2+x monitored by in situ XANES analyses;Dalton Transactions;2024