Access to functionalized alkynylcyclopropanes <i>via</i> reductive radical-polar crossover-based reactions of 1,3-enynes with alkyl radicals-Reference-Cited by-同舟云学术

Access to functionalized alkynylcyclopropanes via reductive radical-polar crossover-based reactions of 1,3-enynes with alkyl radicals

Published:2023 Issue:4 Volume:21 Page:732-737
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Beibei¹,Luo Junfei¹^ORCID,Fang Yewen²³^ORCID

Affiliation:

1. Institute of Mass Spectrometry, School of Materials Science and Chemical Engineering, Ningbo University, No. 818 Fenghua Road, Ningbo 315211, China

2. School of Materials and Chemical Engineering, Ningbo University of Technology, No. 201 Fenghua Road, Ningbo 315211, China

3. Zhejiang Institute of Tianjin University, No. 201 Fenghua Road, Ningbo 315211, China

Abstract

Using SET reduction as the key process, functionalized alkynylcyclopropanes could be accessed via the reactions of 1,3-enynes with alkyl radicals enabled by photoredox or nickel catalysis.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Ningbo

Science and Technology Innovation 2025 Major Project of Ningbo

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB02155B

Reference40 articles.

1. Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations