Molecular heterometallic clusters [Re6−xMoxS8L6] (x = 2–3, L = py, etpy, tbp): negligible influence of the x value on the crystal structures

Author:

Lappi Tatiana I.1ORCID,Gaifulin Yakov M.1ORCID,Sukhikh Taisiya S.1ORCID,Gaifulina Viktoria K.1,Yanshole Vadim V.2ORCID,Cordier Stephane3ORCID,Naumov Nikolay G.1ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave., 630090, Novosibirsk, Russia

2. International Tomography Center, SB RAS, 3A, Institutskaya Str., 630090, Novosibirsk, Russia

3. Univ Rennes I, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, F-35000, France

Abstract

The influence of the metal ratio on the geometric characteristics and crystal structures of heterometallic clusters with {Re6−xMoxQ8} cores was studied. Complexes with the same apical ligands form isostructural packings and form the solid solutions.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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