Molecular heterometallic clusters [Re6−xMoxS8L6] (x = 2–3, L = py, etpy, tbp): negligible influence of the x value on the crystal structures-Reference-Cited by-同舟云学术

Molecular heterometallic clusters [Re_6−xMo_xS₈L₆] (x = 2–3, L = py, etpy, tbp): negligible influence of the x value on the crystal structures

Published:2024 Issue:12 Volume:26 Page:1720-1729
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Lappi Tatiana I.¹^ORCID,Gaifulin Yakov M.¹^ORCID,Sukhikh Taisiya S.¹^ORCID,Gaifulina Viktoria K.¹,Yanshole Vadim V.²^ORCID,Cordier Stephane³^ORCID,Naumov Nikolay G.¹^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Acad. Lavrentiev Ave., 630090, Novosibirsk, Russia

2. International Tomography Center, SB RAS, 3A, Institutskaya Str., 630090, Novosibirsk, Russia

3. Univ Rennes I, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, F-35000, France

Abstract

The influence of the metal ratio on the geometric characteristics and crystal structures of heterometallic clusters with {Re6−xMoxQ8} cores was studied. Complexes with the same apical ligands form isostructural packings and form the solid solutions.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D3CE01229H

Reference27 articles.

1. X-ray Inducible Luminescence and Singlet Oxygen Sensitization by an Octahedral Molybdenum Cluster Compound: A New Class of Nanoscintillators

2. Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications

3. Hexarhenium(III) Clusters [Re6(μ3-S)8X6]4−(X−= Cl−, Br−, I−) are Luminescent at Room Temperature

4. A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes

5. Clustomesogens: Liquid Crystalline Hybrid Nanomaterials Containing Functional Metal Nanoclusters