Site-selective coupling of remote C(sp3)–H/meta-C(sp2)–H bonds enabled by Ru/photoredox dual catalysis and mechanistic studies-Reference-Cited by-同舟云学术

Site-selective coupling of remote C(sp³)–H/meta-C(sp²)–H bonds enabled by Ru/photoredox dual catalysis and mechanistic studies

Published:2022 Issue:18 Volume:13 Page:5382-5389
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Hong-Chao¹,Kong Xiangtao²,Gong Xiao-Ping¹,Li Yuke³^ORCID,Niu Zhi-Jie¹,Gou Xue-Ya¹,Li Xue-Song¹,Wang Yu-Zhao¹,Shi Wei-Yu¹,Huang Yan-Chong¹,Liu Xue-Yuan¹^ORCID,Liang Yong-Min¹^ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

2. Henan Key Laboratory of New Optoelectronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, China

3. Department of Chemistry and Centre for Scientific Modeling and Computation, Chinese University of Hong Kong, Shatin, Hong Kong, China

Abstract

A novel photoinduced Ru/photocatalyst-cocatalyzed regioselective cross-dehydrogenative coupling of dual remote C–H bonds, including inert γ-C(sp3)–H bonds in amides and meta-C(sp2)–H bonds in arenes, to construct meta-alkylated arenes has been accomplished.

Funder

Foundation of Henan Educational Committee

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00764A

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1. Copper-Catalyzed Formal Dehydrogenative Coupling of Carbonyls with Polyfluoroarenes Leading to β-C–H Arylation

2. Pd(II)-Catalyzed para-Selective C–H Arylation of Monosubstituted Arenes