Nanoalloying bulk-immiscible iridium and palladium inhibits hydride formation and promotes catalytic performances

Author:

Zlotea C.1234,Morfin F.5678,Nguyen T. S.5678,Nguyen N. T.9101112,Nelayah J.9101112,Ricolleau C.9101112,Latroche M.1234,Piccolo L.5678

Affiliation:

1. ICMPE

2. Institut de Chimie et des Matériaux de Paris-Est

3. UMR 7182 CNRS & Université Paris Est Créteil

4. 94320 Thiais, France

5. IRCELYON

6. Institut de recherches sur la catalyse et l'environnement de Lyon

7. UMR 5256 CNRS & Université Claude Bernard – Lyon 1

8. 69626 VILLEURBANNE CEDEX, France

9. MPQ

10. Laboratoire Matériaux et Phénomènes Quantiques

11. UMR 7162 CNRS & Université Paris-Diderot

12. 75205 Paris Cedex 13, France

Abstract

Supported Ir–Pd nanoalloys accommodate much less hydrogen than their Ir and Pd counterparts, and exhibit improved performances for the preferential oxidation of CO in hydrogen excess.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Reference48 articles.

1. Nanomaterials for energy conversion and storage

2. Nanoconfined light metal hydrides for reversible hydrogen storage

3. Nanosizing and Nanoconfinement: New Strategies Towards Meeting Hydrogen Storage Goals

4. I. Chorkendorff and J. W.Niemantsverdriet , Concepts of Modern Catalysis and Kinetics , Wiley-VCH , Weinheim , 2nd edn, 2007

5. Z. Paál , Hydrogen effects in catalysis: fundamentals and practical applications , M. Dekker , New York , 1988

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