Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives
Author:
Affiliation:
1. Department of Organic Chemistry
2. Biochemistry and Catalysis
3. Chemistry
4. University of Bucharest
5. Bucharest 030016
6. Instituto Universitario de Tecnología Química CSIC-UPV
7. Universitat Politecnica de Valencia
8. 46022 Valencia
9. Spain
Abstract
Modification of GO by organic molecules changes its catalytic activity in the hydrogen transfer from i-propanol to enones, affecting the selectivity to allyl alcohol and diastereoselectivity to the resulting stereoisomers.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC05105K
Reference32 articles.
1. J. Maes , E. A.Mitchell and B. U. W.Maes, in Green and Sustainable Medicinal Chemistry, ed. L. Summerton, H. F. Sneddon, L. C. Jones and J. H. Clark, RSC, Thomas Graham House, Science Park, Cambridge, 2016, ch. 16, pp. 192–203
2. Heterogeneous Diastereoselective Catalysis - A Powerful Strategy Toward C(15) Stereoselectivity from PGF2α Analogues Structure
3. Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry
4. Critical Assessment of Pharmaceutical ProcessesA Rationale for Changing the Synthetic Route
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