Prolonging the cycling lifetime of lithium metal batteries with a monolithic and inorganic-rich solid electrolyte interphase

Author:

Yang Jinlin1,Li Menghao23,Sun Zejun1,Lian Xu1,Wang Yanan4,Niu Yuxiang1,Jiang Chonglai15,Luo Yani15,Liu Yuan15,Tian Zhangliu1,Long Yu15,Zhang Kun1,Yu Pengcheng16,Zhang Jia7ORCID,Wang Zeheng8ORCID,Wu Gang7ORCID,Gu Meng3,Chen Wei145ORCID

Affiliation:

1. Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore

2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China

3. Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China

4. Department of Physics, National University of Singapore, 2 Science Drive 3, 117542, Singapore

5. Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, P. R. China

6. Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen 518055, China

7. Institute of High-Performance Computing, Agency for Science, Technology and Research, 1 Fusionopolis Way, #16-16 Connexis, Singapore 138632, Singapore

8. School of Electrical Engineering and Telecommunications, The University of New South Wales, Sydney, NSW 2052, Australia

Abstract

A small amount of methoxide additive is found to effectively induce preferential adsorption of anions (i.e., TFSI and NO3) on the surface of the Li metal anode, contributing to an inorganic-rich SEI and enabling stable Li metal batteries.

Funder

Ministry of Education - Singapore

National Natural Science Foundation of China

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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