Back to basics: identification of reaction intermediates in the mechanism of a classic ligand substitution reaction on Vaska's complex-Reference-Cited by-同舟云学术

Back to basics: identification of reaction intermediates in the mechanism of a classic ligand substitution reaction on Vaska's complex

Published:2016 Issue:4 Volume:6 Page:3386-3392
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Durango-García Clara J.¹²³⁴⁵,Jalife Said⁶⁷⁸⁴,Cabellos José Luis⁶⁷⁸⁴,Martínez Saul H.⁶⁷⁸⁴,Jimenez-Halla J. Oscar C.⁹¹⁰¹¹⁴,Pan Sudip¹²¹³¹⁴,Merino Gabriel⁶⁷⁸⁴,Montiel-Palma Virginia¹²³⁴

Affiliation:

1. Centro de Investigaciones Químicas

2. Universidad Autónoma del Estado de Morelos

3. Cuernavaca

4. Mexico

5. Facultad de Ciencias

6. Departamento de Física Aplicada

7. CINVESTAV Unidad Mérida

8. Mérida 97310

9. Departamento de Química (DCNE)

10. Universidad de Guanajuato

11. Guanajuato

12. Department of Chemistry and Center for Theoretical Studies

13. Indian Institute of Technology Kharagpur

14. India

Abstract

The mechanism of methylation of Vaska's complextrans-[ClIr(CO)(PPh₃)₂] by trimethylgallium was studied and the identification of the spectroscopically detected intermediates was achieved with the aid of computational methods.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA20969B

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