Insight into the atomic structure of Li2MnO3 in Li-rich Mn-based cathode materials and the impact of its atomic arrangement on electrochemical performance

Author:

Song Yuanzhe12345,Zhao Xuebing12345,Wang Chao12345,Bi Han12345,Zhang Jie12345,Li Sesi12345,Wang Min12345,Che Renchao12345ORCID

Affiliation:

1. Laboratory of Advanced Materials

2. Department of Materials Science

3. Collaborative Innovation Center of Chemistry for Energy Materials

4. Fudan University

5. Shanghai 200438

Abstract

Local heterogeneity in crystal lattice is directly observed in synthesized Li2MnO3/LiMO2 (M = Ni, Mn) cathode materials. With SAED application, for the first time, we accordingly uncover that the lattice heterogeneity is induced by different Li2MnO3 atomic arrangements coexisting in same crystal domain.

Funder

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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