Crystalline, room-temperature stable phosphine–SO2 adducts: generation of sulfur monoxide from sulfur dioxide
Author:
Affiliation:
1. Institut für Anorganische und Analytische Chemie
2. Westfälische Wilhelms-Universität Münster
3. 48149 Münster
4. Germany
5. Organisch-Chemisches Institut
Abstract
Particularly basic phosphines form isolable Lewis base adducts with SO2 that readily release SO at room temperature driven by the formation of the corresponding phosphine oxides.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01484A
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3. Mechanistic study on the atmospheric formation of acid rain base on the sulfur dioxide
4. DABCO-Bis(sulfur dioxide), DABSO, as a Convenient Source of Sulfur Dioxide for Organic Synthesis: Utility in Sulfonamide and Sulfamide Preparation
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