Modulating the cobalt redox potential through imidazole hydrogen bonding interactions in a supramolecular biomimetic protein-cofactor model
Author:
Affiliation:
1. Department of Chemistry, University of Zurich
2. Zurich
3. Switzerland
Abstract
This paper describes a supramolecular biomimetic model of the “His-on” configuration and the charge relay system present in certain types of B12-dependent enzymes.
Funder
Swiss National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04396D
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