Multiscale structural control of linked metal–organic polyhedra gel by aging-induced linkage-reorganization

Author:

Wang Zaoming12ORCID,Villa Santos Christian3,Legrand Alexandre1ORCID,Haase Frederik1,Hara Yosuke4ORCID,Kanamori Kazuyoshi4ORCID,Aoyama Takuma5,Urayama Kenji5ORCID,Doherty Cara M.6ORCID,Smales Glen J.7,Pauw Brian R.7,Colón Yamil J.3ORCID,Furukawa Shuhei12ORCID

Affiliation:

1. Institute for Integrated Cell-Material Science (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

2. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

3. Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556, USA

4. Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, Japan

5. Department of Macromolecular Science and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

6. Manufacturing, Commonwealth Scientific and Industrial Research Organisation, Clayton South, Victoria, Australia

7. Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12205 Berlin, Germany

Abstract

By a controlled post-synthetic aging process, we demonstrate a protocol to induce the linkage reorganization in metal–organic polyhedra-linked gel networks, leading to the control of gel structures over multiple length scales and their properties.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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