Hydrogen bonds, and σ-hole and π-hole bonds – mechanisms protecting doublet and octet electron structures

Author:

Grabowski Sławomir J.12345ORCID

Affiliation:

1. Faculty of Chemistry

2. University of the Basque Country and Donostia International Physics Center (DIPC)

3. P.K. 1072 20080 Donostia

4. Spain

5. IKERBASQUE

Abstract

For various interactions electron charge shifts try to protect the former doublet or octet electronic structure of the Lewis acid centre.

Funder

Eusko Jaurlaritza

Ministerio de Economía y Competitividad

Federación Española de Enfermedades Raras

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference175 articles.

1. Molecular Interactions. From van der Waals to Strongly, Bound Complexes , ed. S. Scheiner , John Wiley & Sons , Chichester , 1997

2. Binding Mechanisms in Supramolecular Complexes

3. P. Hobza and K.Müller-Dethlefs , Non-Covalent Interactions, Theory and Experiment , Royal Society of Chemistry , Thomas Graham House, Science Park, Milton Road, Cambridge, United Kingdom , 2010

4. Perspectives on halogen bonding and other σ-hole interactions: Lex parsimoniae (Occam’s Razor)

5. G. A. Jeffrey , An Introduction to Hydrogen Bonding , Oxford University Press , New York , 1997

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