Metallosupramolecular Ni2L3 and Ni4L6 complexes of bis-bidentate pyridine-containing ligands: X-ray structures and catalytic proton reduction
Author:
Affiliation:
1. Department of Biology and Chemistry
2. City University of Hong Kong
3. Kowloon
4. China
Abstract
The pyridine-containing ligands L1 and L2 react with Ni2+ ions to afford dinuclear triple-stranded helicate and tetrahedral cage supramolecular complexes, respectively; the two architectures exhibit contrasting reactivity towards electro- and photocatalytic proton reduction.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01706H
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