An [Fe<sup>III</sup><sub>8</sub>] molecular oxyhydroxide-Reference-Cited by-同舟云学术

An [Fe^III₈] molecular oxyhydroxide

Published:2022 Issue:23 Volume:51 Page:8945-8948
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cutler Daniel J.¹^ORCID,Coletta Marco¹^ORCID,Singh Mukesh K.¹^ORCID,Canaj Angelos B.¹^ORCID,McCormick Laura J.²^ORCID,Coles Simon J.²^ORCID,Schnack Jürgen³^ORCID,Brechin Euan K.¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, Scotland, UK

2. EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK

3. Universitat Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany

Abstract

An [FeIII8] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state, S = 10.

Funder

Engineering and Physical Sciences Research Council

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01477G

Reference40 articles.

1. Magneto-Structural Correlations in Linear and Bent Oxo-Bridged Transition-Metal Dimers: Comparisons, Interpretations, and Predictions of Ground-State Magnetic Properties

2. Molecular spin frustration in the [Fe4O2]8+ core: synthesis, structure, and magnetochemistry of tetranuclear iron-oxo complex [Fe4O2(O2CR)7(bpy)2](C1O4) (R = Me, Ph)

3. Large Spin Differences in Structurally Related Fe6 Molecular Clusters and Their Magnetostructural Explanation

4. Single-molecule magnets based on iron(iii) oxo clusters

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