Facile access to amino-substituted cyclopentafullerenes: novel reaction of [60]fullerene with β-substituted propionaldehydes and secondary amines in the absence/presence of magnesium perchlorate

Author:

Li Yun-Fei12345,Wang Kun12345,Wang Hui-Juan678910,Li Fa-Bao12345ORCID,Sun Rui12345,Li Jia-Xing111291314ORCID,Liu Li12345ORCID,Liu Chao-Yang678910,Asiri Abdullah M.1516171819ORCID

Affiliation:

1. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules

2. Hubei Key Laboratory of Polymer Materials

3. and School of Chemistry and Chemical Engineering

4. Hubei University

5. Wuhan 430062

6. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics

7. Wuhan Center for Magnetic Resonance

8. Wuhan Institute of Physics and Mathematics

9. Chinese Academy of Sciences

10. Wuhan 430071

11. Key Laboratory of Novel Thin Film Solar Cells

12. Institute of Plasma Physics

13. Hefei 230031

14. People's Republic of China

15. Department of Chemistry

16. Faculty of Science

17. King Abdulaziz University

18. Jeddah 21589

19. Saudi Arabia

Abstract

Reaction of [60]fullerene with β-substituted propionaldehydes and secondary amines in the absence/presence of magnesium perchlorate afforded a series of novel amino-substituted cyclopentafullerenes without/with two additional carbons.

Funder

National Natural Science Foundation of China

Wuhan University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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