Metal-free alkynylsulfonylation of vinylarenes

Author:

Wang Fei12345,Zhou Huan12345,Li Yajun12345,Bao Hongli12345ORCID

Affiliation:

1. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology

2. State Key Laboratory of Structural Chemistry

3. Center for Excellence in Molecular Synthesis

4. Fujian Institute of Research on the Structure of Matter

5. University of Chinese Academy of Sciences

Abstract

A metal-free two-component alkynylsulfonylation of vinylarenes with aryl alkynylsulfones to afford various β-sulfonyl alkynes in moderate to excellent yields under mild conditions is developed.

Funder

National Natural Science Foundation of China

Haixi Institute, Chinese Academy of Sciences

Fujian Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference86 articles.

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2. F. Bernardi , I. G.Csizmadia and A.Mangini , Organic Sulfur Chemistry. Theoretical and Experimental Advances , Elsevier , Amsterdam , 1985

3. S. Patai , Z.Rappoport and C. J. M.Stirling , The Chemistry of Sulphones and Sulphoxides , Wiley , New York , 1988

4. G. H. Whitham , Organosulfur Chemistry , Oxford University Press , Oxford/New York , 1995

5. The Stereochemistry of the Addition of Mesitylenethiol to Mesitylacetylene1-3

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