Uniaxial thermal expansion behaviors and ionic conduction in a layered (NH4)2V3O8-Reference-Cited by-同舟云学术

Uniaxial thermal expansion behaviors and ionic conduction in a layered (NH4)2V3O8

Published:2020 Issue:30 Volume:49 Page:10638-10644
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yao Zhi-Yuan¹²³⁴,Zhang Guo-Qin¹²³⁴,Yao Wan-Wan¹²³⁴,Wang Xiao-Zu⁵²³⁴,Qian Yin¹²³⁴,Ren Xiao-Ming¹²³⁴⁶^ORCID

Affiliation:

1. State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering

2. Nanjing Tech University

3. Nanjing 211816

4. P. R. China

5. College of Chemical Engineering

6. College of Materials Science and Engineering

Abstract

Layered (NH₄)₂V₃O₈ exhibits ZTE and NTE behaviors along the c-axis, and ZTE nature along the a-axis owing to swing-like movement of vanadyl in VO₄ tetrahedra and transverse vibration of bridged O atoms connecting VO₄ tetrahedra.

Funder

Priority Academic Program Development of Jiangsu Higher Education Institutions

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01833C

Reference43 articles.

1. Negative thermal expansion in functional materials: controllable thermal expansion by chemical modifications

2. Systematic and Controllable Negative, Zero, and Positive Thermal Expansion in Cubic Zr1–xSnxMo2O8

3. A combined stretching–tilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(ii)-MOF

4. A Material Showing Colossal Positive and Negative Volumetric Thermal Expansion with Hysteretic Magnetic Transition

5. Zero Thermal Expansion and Ferromagnetism in Cubic Sc1–xMxF3 (M = Ga, Fe) over a Wide Temperature Range

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