Synthesis and evaluation of new modified diglycolamides with different stereochemistry for extraction of tri- and tetravalent metal ions

Author:

Diaz Gomez Laura1ORCID,Wilden Andreas1ORCID,Schneider Dimitri1ORCID,Paparigas Zaina1ORCID,Modolo Giuseppe1ORCID,Gullo Maria Chiara2ORCID,Huskens Jurriaan2ORCID,Verboom Willem2ORCID

Affiliation:

1. Forschungszentrum Jülich GmbH, Institut für Energie und Klimaforschung, Nukleare Entsorgung (IEK-6), 52428 Jülich, Germany

2. Laboratory of Molecular Nanofabrication, Department for Molecules & Materials, Mesa+ Institute for Nanotechnology, University of Twente, 7500 AE Enschede, The Netherlands

Abstract

The syn- or anti-orientation of backbone substituents determines the affinity and selectivity of novel diglycolamide diastereomers in actinide and lanthanide extraction from HNO3.

Funder

Bundesministerium für Umwelt, Naturschutz, nukleare Sicherheit und Verbraucherschutz

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference47 articles.

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3. M.Miguirditchian , L.Chareyre , X.Heres , C.Hill , P.Baron and M.Masson , Global, 2007, Advanced Nuclear Fuel Cycles and Systems , Boise, ID , United States , 2007

4. R.Malmbeck , M.Carrott , B.Christiansen , A.Geist , X.Hérès , D.Magnusson , G.Modolo , C.Sorel , R.Taylor and A.Wilden , Sustainable Nuclear Energy Conference , Manchester , UK , 2014

5. Development of a New Flowsheet for Co-Separating the Transuranic Actinides: The “EURO-GANEX” Process

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