Molecular brass: Cu4Zn4, a ligand protected superatom cluster-Reference-Cited by-同舟云学术

Molecular brass: Cu4Zn4, a ligand protected superatom cluster

Published:2014 Issue:63 Volume:50 Page:8681-8684
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Freitag Kerstin¹²³,Banh Hung¹²³,Gemel Christian¹²³,Seidel Rüdiger W.¹²³,Kahlal Samia⁴⁵⁶,Saillard Jean-Yves⁴⁵⁶,Fischer Roland A.¹²³

Affiliation:

1. Inorganic Chemistry II

2. Ruhr-University Bochum

3. 44801 Bochum, Germany

4. Institut des Sciences Chimiques de Rennes - UMR 6226

5. Université de Rennes 1

6. 35042 Rennes Cedex, France

Abstract

The first examples of structurally characterized “molecular brass”, [(CuCN^tBu)₄(ZnCp*)₄] and [(CuCN^tBu)₄(ZnCp*)₃ZnCp] exhibit the structural motif of a [Cu₄Zn₄] tetrahedral star, which is inversely found in the γ-brass phase Cu₅Zn₈.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC03401E

Reference21 articles.

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