Novel quadrilateral-pore 2D-COFs as visible-light driven catalysts evaluated by the descriptor of integrated pz-orbital population

Author:

Zhang Rui12,Wang Zhi-Wei1,Yang Zhao-Di2ORCID,Bai Fu-Quan134ORCID

Affiliation:

1. International Joint Research Laboratory of Nano-Micro Architecture Chemistry, Institute of Theoretical Chemistry and College of Chemistry, Jilin University, Changchun 130023, People's Republic of China

2. School of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, People's Republic of China

3. Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), Jilin University, Changchun 130023, People's Republic of China

4. Beijing National Laboratory for Molecular Sciences, Beijing 100013, People's Republic of China

Abstract

Novel quadrilateral-pore 2D-COFs are capable of driving the HER spontaneously under visible-light irradiation, evaluated by a catalytic descriptor (integrated pz-orbital population).

Funder

Natural Science Foundation of Heilongjiang Province

Education Department of Jilin Province

Jilin University

Beijing National Laboratory for Molecular Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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