Activation of carbon dioxide by new mixed sandwich uranium(iii) complexes incorporating cyclooctatetraenyl and pyrrolide, phospholide, or arsolide ligands-Reference-Cited by-同舟云学术

Activation of carbon dioxide by new mixed sandwich uranium(iii) complexes incorporating cyclooctatetraenyl and pyrrolide, phospholide, or arsolide ligands

Published:2015 Issue:10 Volume:39 Page:7602-7607
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kahan Rachel J.¹²³⁴⁵,Cloke F. Geoffrey N.¹²³⁴⁵,Roe S. Mark¹²³⁴⁵,Nief François⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry

2. School of Life Sciences

3. University of Sussex

4. Brighton

5. UK

6. École Polytechnique

7. CNRS

8. Route de Saclay

9. F-91128 Palaiseau

10. France

Abstract

Mixed-sandwich complexes of the type [U(COT^TIPS2)(Cp^EMe4)] (where E is N or P and COT^TIPS2 = C₈H₆{1,4-SiⁱPr₃}) both reduce and insert CO₂ to afford dimeric, oxo-bridged, uranium carbamate and phosphacarbonate complexes.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00590F

Reference37 articles.

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3. Synthesis and structural characterisation of lanthanide and actinide phosphaorganometallic complexes derived from the 3,5-di-tert-butyl-1,2,4-triphospholyl ring anion, P3C2But−2: Crystal and molecular structures of [M(η5-P3C2But2)2(η2-P3C2But2)] (M=Sc, Y, Tm, and U)