Radical addition of ketones and cyanide to olefinsviaacid catalyzed formation of intermediate alkenyl peroxides
Author:
Affiliation:
1. Max Planck Institut für Kohlenforschung
2. 45470 Mülheim an der Ruhr
3. Germany
4. Universität zu Köln
5. Department für Chemie
6. 50939 Köln
Abstract
γ-Cyanoketones are formed by double radical addition from olefins, ketones and sulfonyl cyanidesviareactive alkenyl peroxide intermediates.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00447E
Reference70 articles.
1. Recent Advances in Radical Difunctionalization of Simple Alkenes
2. Atom Transfer Radical Reactions as a Tool for Olefin Functionalization – On the Way to Practical Applications
3. Factors Controlling the Addition of Carbon‐Centered Radicals to Alkenes—An Experimental and Theoretical Perspective
4. Formation of CC Bonds by Addition of Free Radicals to Alkenes
5. Acid-Catalyzed Oxidative Radical Addition of Ketones to Olefins
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