On the structures of the rare-earth metal germanides from the series REAl1−xGe3(RE = Nd, Sm, Gd, Tb, Dy, Ho; 0.6 < x < 0.9). A tale of vacancies at the Al sites and the concomitant structural modulations

Author:

Zhang Jiliang1234,Liu Yanyan56789,Shek Chan Hung101112,Wang Yingmin56789,Bobev Svilen1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Delaware

3. Newark

4. USA

5. Key Laboratory of Materials Modification by Laser

6. Ion

7. and Electron Beams (Dalian University of Technology)

8. Ministry of Education

9. Dalian University of Technology

10. Department of Physics and Materials Science

11. City University of Hong Kong

12. Kowloon

Abstract

This paper discusses the germanides with the general formula REAl1−xGe3(RE = Nd, Sm, Gd–Ho), whose average structure is a defect-variant of the orthorhombic SmNiGe3.

Funder

Division of Materials Research

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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