CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium–iodonium ylide withp-methoxyphenylacetylene-Reference-Cited by-同舟云学术

CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium–iodonium ylide withp-methoxyphenylacetylene

Published:2019 Issue:45 Volume:9 Page:26219-26223
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Levina Irina I.¹²³,Tarasov Valery F.⁴²³,Podrugina Tatyana A.¹²³⁵⁶,Nekipelova Tatiana D.¹²³^ORCID

Affiliation:

1. Emanuel Institute of Biochemical Physics RAS

2. Moscow

3. Russia

4. Semenov Institute of Chemical Physics RAS

5. Department of Chemistry

6. Lomonosov Moscow State University

Abstract

CIDNP in³¹P NMR spectra of major products in the course of the reaction between phosphonium–iodonium ylide andp-methoxyphenylacetylene reveals the mechanism of products formationviaradical pair.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA05697A

Reference23 articles.

1. Hypervalent iodine. Mixed iodonium ylides

2. Heterocycles from Phosphonium−Iodonium Ylides. Photochemical Synthesis of λ5-Phosphinolines

3. Hetaryl-Substituted Phosphonium-Iodonium Ylides in Synthesis of Heterocycles

4. Annelated P-containing heterocycles from aryl- and hetaryl-substituted phosphonium iodonium ylides with a methoxycarbonyl-group

5. Furyl-Substituted Mixed Phosphonium-Iodonium Ylides in the Synthesis of Annelated P-Containing Heterocyclic Compounds

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