Spatially-ordered nano-sized crystallites formed by dehydration-induced single crystal cracking of CuCl2·2(H2O)-Reference-Cited by-同舟云学术

Spatially-ordered nano-sized crystallites formed by dehydration-induced single crystal cracking of CuCl2·2(H2O)

Published:2018 Issue:39 Volume:20 Page:6005-6017
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Chizhik Stanislav¹²³⁴⁵^ORCID,Matvienko Alexander¹²³⁴⁵^ORCID,Sidelnikov Anatoly¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Solid State Chemistry and Mechanochemistry

2. Siberian Branch of Russian Academy of Sciences

3. Novosibirsk 620128

4. Russian Federation

5. Novosibirsk State University

Abstract

The dehydration of CuCl₂·2(H₂O) crystals is studied as an example of a fracture-assisted chemical reaction. The structure of the combined reaction–fracture front undergoes a spontaneous morphology transition, leading to spatial ordering and 8-fold acceleration of the reaction.

Funder

Russian Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE00683K

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