Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds-Reference-Cited by-同舟云学术

Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

Published:2019 Issue:19 Volume:55 Page:2809-2812
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fernández-Galán Rafael¹²³⁴⁵^ORCID,Ramos Alberto¹²³⁴⁵^ORCID,Huergo Estefanía¹²³⁴⁵,Antiñolo Antonio¹²³⁴⁵^ORCID,Carrillo-Hermosilla Fernando¹²³⁴⁵^ORCID,Rodríguez-Diéguez Antonio²⁶⁷⁸⁹^ORCID,García-Vivó Daniel¹⁰¹¹¹²¹³^ORCID

Affiliation:

1. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

2. Departamento de Química Inorgánica

3. Orgánica y Bioquímica

4. Facultad de Ciencias y Tecnologías Químicas

5. Universidad de Castilla-La Mancha

6. Facultad de Ciencias

7. Universidad de Granada

8. Avenida de la Fuente Nueva S/N

9. 18071 Granada

10. Departamento de Química Orgánica e Inorgánica/IUQOEM

11. Universidad de Oviedo

12. E-33071 Oviedo

13. Spain

Abstract

N,N′-Phosphinoguanidinate Al compounds rearrange under mild conditions to phosphinimine-amidinato derivatives via an unprecedented carbodiimide de-insertion followed by [3+2] cycloaddition.

Funder

Ministerio de Economía y Competitividad

Universidad de Castilla-La Mancha

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00432G

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