Stibine-protected Au13nanoclusters: syntheses, properties and facile conversion to GSH-protected Au25nanocluster-Reference-Cited by-同舟云学术

Stibine-protected Au13nanoclusters: syntheses, properties and facile conversion to GSH-protected Au25nanocluster

Published:2018 Issue:46 Volume:9 Page:8723-8730
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Ying-Zhou¹²³^ORCID,Ganguly Rakesh¹²³^ORCID,Hong Kar Yiu¹²³,Li Yongxin¹²³,Tessensohn Malcolm Eugene¹²³,Webster Richard¹²³,Leong Weng Kee¹²³^ORCID

Affiliation:

1. Division of Chemistry & Biological Chemistry

2. Nanyang Technological University

3. Singapore

Abstract

Monostibine-protected ionic Au₁₃nanoclusters, namely, [Au₁₃(L)₈(Cl)₄][Cl] (L = SbPh₃,2a·Cl; Sb(p-tolyl)₃,2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH₄in dichloromethane.

Funder

Agency for Science, Technology and Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC03132K

Reference87 articles.

1. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution

2. Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties

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4. Total Structure Determination of Thiolate-Protected Au38 Nanoparticles

5. First enantioseparation and circular dichroism spectra of Au38 clusters protected by achiral ligands

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