A binary catalyst system of a cationic Ru–CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide-Reference-Cited by-同舟云学术

A binary catalyst system of a cationic Ru–CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide

Published:2016 Issue:79 Volume:52 Page:11842-11845
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ng Chee Koon¹²³⁴⁵,Wu Jie⁶⁷⁸⁴,Hor T. S. Andy⁵⁹¹⁰¹¹⁴,Luo He-Kuan⁵⁹¹⁰¹¹⁴

Affiliation:

1. NUS Graduate School for Integrative Sciences and Engineering

2. Center for Life Sciences

3. 28 Medical Drive Singapore 117456

4. Singapore

5. Institute of Materials Research and Engineering

6. Department of Chemistry

7. National University of Singapore

8. Singapore 117543

9. Agency for Science

10. Technology and Research

11. Singapore 138634

Abstract

Binary catalyst systems comprising a cationic Ru–CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO₂ at r.t. and 1 atm CO₂, with [Ru(CNC_Bn)(CO)₂(H)][PF₆] and KOCO₂^tBu producing formoxyborane in 76% yield.

Funder

Agency for Science, Technology and Research

Science and Engineering Research Council, Agency for Science, Technology and Research

Institute of Materials Research and Engineering - A STAR

Economic Development Board - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC06278D

Reference39 articles.

1. Efficient Activation of the Greenhouse Gas CO2

2. Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide

3. Recent progress in catalytic conversions of carbon dioxide

4. Recent Advances in Carbon Dioxide Capture, Fixation, and Activation by using N-Heterocyclic Carbenes

5. Using carbon dioxide as a building block in organic synthesis

Cited by 25 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Zinc-Catalyzed Hydroboration of Carbon Dioxide Amplified by Borane-Tethered Heteroscorpionate Bis(Pyrazolyl)methane Ligands;Inorganic Chemistry;2024-04-24

2. Panoramic Mechanistic Insights into Hydrogen Production via Aqueous-Phase Reforming of Methanol Catalyzed by Ruthenium Complexes of Bis-N-Heterocyclic Carbene Pincer Ligands;ACS Catalysis;2024-02-17

3. Catalysis by Pincer Compounds and Their Contribution to Environmental and Sustainable Processes;Catalysis for a Sustainable Environment;2024-02-15

4. Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO₂ with Catecholborane;Organometallics;2023-05-18

5. Iron-Catalyzed Selective Hydroboration of CO₂ by Cooperative B–H Bond Activation;Organometallics;2023-05-09