Synthesis and coordination chemistry of 1,1,1-tris-(pyrid-2-yl)ethane

Abstract

The complexes [ML₂]ⁿ⁺(Mⁿ⁺= Fe²⁺, Co²⁺, Co³⁺, Cu²⁺and Ag⁺), [PdCl₂L] and [CuI(L)] are described. [AgL₂]⁺is an unusual square planar silver(i) centre (left). Exposure of [CuI(L)] to air affords mono- or dinuclear copper(ii)/carbonato products. Two of the copper complexes form crystalline hydrates with complicated hydrogen bond networks (right).