Direct method to grasp molecular topology of mesogens through13C–1H dipolar couplings

Author:

Reddy M. Kesava1,Shalini P. Jaya1,Lobo Nitin P.23ORCID,Roy Arun4ORCID,Narasimhaswamy T.13ORCID

Affiliation:

1. Polymer Science and Technology, CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India

2. Centre for Analysis, Testing, Evaluation & Reporting Services (CATERS), CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India

3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, Uttar Pradesh 201002, India

4. Soft Condensed Matter, Raman Research Institute, Bangalore, 560080, India

Abstract

The utility of13C–1H dipolar couplings obtained from the 2D NMR spectrum is demonstrated in classifying the molecular topology of three topologically variant thermotropic liquid crystals in their liquid crystalline phase.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference35 articles.

1. J. W.Goodby , E. J.Davis , R. J.Mandle and S. J.Cowling , in Handbook of Liquid Crystals: 8 Volume Set , ed. J. W. Goodby , P. J. Collings , T. Kato , C. Tschierske , H. Gleeson and P. Raynes , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , Second edn, 2014 , pp. 1–30

2. Handbook of liquid crystals, Non-Conventional Liquid Crystals , ed. J. W. Goodby , P. J. Collings , T. Kato , C. Tschierske , H. F. Gleeson and P. Raynes , Wiley-VCH Verlag & Co. KGaA , Weinheim, Germany, II , 2014 , vol. 5

3. D.Dunmur and G.Luckhurst , in Handbook of Liquid Crystals: 8 Volume Set , ed. J. W. Goodby , P. J. Collings , T. Kato , C. Tschierske , H. Gleeson and P. Raynes , Wiley-VCH Verlag & Co. KGaA , Weinheim, Germany , Second, 2014 , pp. 1–39

4. A Comparative 13C NMR Study of Local Ordering in a Homologous Series of Bent-core Liquid Crystals

5. Order and dynamics of rod-like and banana-shaped liquid crystals by 2H NMR

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