Low temperature structures and magnetic interactions in the organic-based ferromagnetic and metamagnetic polymorphs of decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide, [FeCp*2]˙+[TCNQ]˙−-Reference-Cited by-同舟云学术

Low temperature structures and magnetic interactions in the organic-based ferromagnetic and metamagnetic polymorphs of decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide, [FeCp*2]˙+[TCNQ]˙−

Published:2021 Issue:32 Volume:50 Page:11228-11242
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lapidus Saul H.¹^ORCID,Stephens Peter W.¹^ORCID,Fumanal Maria²,Ribas-Ariño Jordi²,Novoa Juan J.²,DaSilva Jack G.³,Rheingold Arnold L.⁴,Miller Joel S.³^ORCID

Affiliation:

1. Department of Physics & Astronomy, Stony Brook University, Stony Brook, New York 11794-3800, USA

2. Department of Materials Chemistry and Physical Chemistry and IQTCUB, University of Barcelona, Av. Diagonal, 645, E-08028, Barcelona, Spain

3. Department of Chemistry, University of Utah, 315 S. 1400 E. RM 2020, Salt Lake City, UT 84112-0850, USA

4. Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, USA

Abstract

To identify the genesis of the differing magnetic behaviors for the ferro- (FO) and metamagnetic (MM) polymorphs of [FeCp*2][TCNQ] the low temperature structures of each polymorph were determined from high-resolution synchrotron powder diffraction data.

Funder

U.S. Department of Energy

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02106K

Reference41 articles.

1. Molecular Materials I. Molecular materials mimic inorganic network solids

2. Molecular ferromagnets