Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation-Reference-Cited by-同舟云学术

Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation

Published:2016 Issue:22 Volume:18 Page:15118-15132
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sleiman Chantal¹²³⁴⁵,González Sergio⁶⁷⁸⁹¹⁰,Klippenstein Stephen J.¹¹¹²¹³¹⁴,Talbi Dahbia¹⁵¹⁶¹⁷¹⁸,El Dib Gisèle¹²³⁴⁵,Canosa André¹²³⁴⁵

Affiliation:

1. Département de Physique Moléculaire

2. Institut de Physique de Rennes

3. UMR 6251 du CNRS - Université de Rennes 1

4. Bat. 11C

5. Campus de Beaulieu

6. Departamento de Química Física

7. Facultad de Ciencias y Tecnologías Químicas

8. Universidad de Castilla La Mancha

9. Campus Universitario

10. 13071 Ciudad Real

11. Argonne National Laboratory

12. Chemical Sciences and Engineering Division

13. Argonne

14. USA

15. Laboratoire Univers et Particules de Montpellier – UMR 5299 du CNRS - Université de Montpellier

16. Campus Triolet

17. 34095 Montpellier Cedex 05

18. France

Abstract

The gas phase reaction between the CN radical and acetonitrile CH₃CN was investigated experimentally with a CRESU apparatus and a slow flow reactor as well as theoretically to explore the temperature and pressure dependence of its rate coefficient from 354 K down to 23 K.

Funder

Conseil Régional de Bretagne

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP01982J

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1. ACE-FTS observations of acetonitrile in the lower stratosphere

2. New Millimeter Heterodyne Observations of Titan: Vertical Distributions of Nitriles HCN, HC3N, CH3CN, and the Isotopic Ratio 15N/14N in Its Atmosphere

3. Ion chemistry and N-containing molecules in Titan's upper atmosphere

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