High electron affinity triggered by lithium coordination: quasi-chalcogen properties of Li<sub>2</sub>Sn<sub>8</sub>Be-Reference-Cited by-同舟云学术

High electron affinity triggered by lithium coordination: quasi-chalcogen properties of Li₂Sn₈Be

Published:2022 Issue:17 Volume:24 Page:10611-10621
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xue Duomei¹^ORCID,Chen Zeren²,Liu Jingyao¹^ORCID,Wu Di¹^ORCID,Li Zhiru¹^ORCID,Li Ying¹^ORCID

Affiliation:

1. Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China

2. School of Mechanical and Aerospace Engineering, Jilin University, Changchun 130025, P. R. China

Abstract

A new superatom, namely Li2Sn8Be, has been characterized. What is extraordinary is that the introduction of Li ligands to Sn8Be endows the system with a high electron affinity and remarkable similarity to chalcogen elements.

Funder

National Natural Science Foundation of China

Jilin University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00967F

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