Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(iii) complex-Reference-Cited by-同舟云学术

Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(iii) complex

Published:2014 Issue:41 Volume:43 Page:15391-15397
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Nagao Hirotaka¹²,Shimura Naoto¹²,Yonezawa Haruka¹²

Affiliation:

1. Sophia University

2. Tokyo 102-8554, Japan

Abstract

Oxidation of the facial-type trichloridoruthenium(iii) complex bearing ethylbis(2-pyridylmethyl)amine (ebpma), fac-[Ru^IIICl₃(ebpma)], with (NH₄)₂[Ce^IV(NO₃)₆] in acetonitrile afforded a ruthenium(iii) complex having bis(2-pyridylcarbonyl)aminato (bpca), [Ru^IIICl₂(NCCH₃)(bpca)]. The bpca moiety showed interactions with cations such as protons.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01842G

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