A comparative study on the reactivity of ditantalum deuteride cluster anions Ta2D2− and Ta2D4− toward N2-Reference-Cited by-同舟云学术

A comparative study on the reactivity of ditantalum deuteride cluster anions Ta₂D₂⁻ and Ta₂D₄⁻ toward N₂

Published:2022 Issue:40 Volume:24 Page:24950-24958
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cheng Xin¹²³,Li Zi-Yu¹³,Mou Li-Hui¹²³,Liu Qing-Yu¹³,He Sheng-Gui¹²³^ORCID

Affiliation:

1. State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

2. University of Chinese Academy of Sciences, Beijing, 100049, P. R. China

3. Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing, 100190, P. R. China

Abstract

The liberation of a single D atom in N2 activation by gas-phase clusters was identified for the first time in the reactions of Ta2D2,4− with N2, and Ta2D4− is much more reactive than Ta2D2−.

Funder

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02248F

Reference80 articles.

1. M.Appl , Ammonia: principles and industrial practice , Wiley-VCH Verlag GmbH , 1999

2. How a century of ammonia synthesis changed the world

3. Dinitrogen Coordination Chemistry: On the Biomimetic Borderlands

4. The continuing story of dinitrogen activation

5. Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Toward Designing Reactive Metal Clusters for Dinitrogen Activation: A Guideline Based on N₂ Initial Adsorption;Inorganic Chemistry;2024-05-28

2. Activation of Dinitrogen Promoted by Adsorption of C₆H₆ on Fe₂VC^– Cluster Anions;The Journal of Physical Chemistry Letters;2023-07-11