Impacts of heteroatom substitution on the excited state dynamics of π-extended helicenes-Reference-Cited by-同舟云学术

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Impacts of heteroatom substitution on the excited state dynamics of π-extended helicenes

Published:2024 Issue:18 Volume:6 Page:4567-4571
ISSN:2516-0230
Container-title:Nanoscale Advances
language:en
Short-container-title:Nanoscale Adv.

Author:

Kondo Yuto¹,Tsutsui Yusuke¹²^ORCID,Matsuo Yusuke¹,Tanaka Takayuki¹^ORCID,Seki Shu¹^ORCID

Affiliation:

1. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

2. JST-PRESTO, Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

The excited state dynamics of heterohelicenes [9]TH and [9]AH were spectroscopically studied. [9]AH showed enhanced fluorescence, while phosphorescence occurred in [9]TH due to its enhanced spin–orbit coupling and swift intersystem crossing.

Funder

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NA/D4NA00516C

Reference38 articles.

1. Curved Pi-Conjugation, Aromaticity, and the Related Chemistry of Small Fullerenes (

2. Bowls, Hoops, and Saddles: Synthetic Approaches to Curved Aromatic Molecules

3. Dibenzo[ghi,mno]fluoranthene

4. Corannulene. A convenient new synthesis

5. Synthesis of a carbon nanobelt

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