Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes-Reference-Cited by-同舟云学术

Understanding mechanism driven regioselectivity in zirconium-catalysed hydroaminoalkylation: homoallylic amines from conjugated dienes

Published:2024 Issue:27 Volume:15 Page:10571-10576
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nuñez Bahena Erick¹^ORCID,Hosseini Kimia¹^ORCID,Curto Sheila Galván¹^ORCID,Schafer Laurel L.¹^ORCID

Affiliation:

1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1

Abstract

A change in regioselectivity for group 4 catalysed hydroaminoalkylation gives linear homoallylic amines from conjugated dienes and amines. Isolated reaction intermediates provide mechanistic insight and evidence for reversible C–C bond formation.

Funder

University of British Columbia

Natural Sciences and Engineering Research Council of Canada

Mitacs

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00636D

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