Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding-Reference-Cited by-同舟云学术

Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding

Published:2016 Issue:35 Volume:52 Page:5932-5935
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Isla Helena¹²³⁴⁵,Srebro-Hooper Monika⁶⁷⁸⁹¹⁰,Jean Marion¹¹¹²¹³¹⁴¹⁵,Vanthuyne Nicolas¹¹¹²¹³¹⁴¹⁵,Roisnel Thierry¹²³⁴⁵,Lunkley Jamie L.¹⁶¹⁷¹⁸¹⁹,Muller Gilles¹⁶¹⁷¹⁸¹⁹,Williams J. A. Gareth¹⁶²⁰²¹²²^ORCID,Autschbach Jochen¹⁶²³²⁴²⁵¹⁹,Crassous Jeanne¹²³⁴⁵

Affiliation:

1. Institut des Sciences Chimiques de Rennes

2. UMR 6226

3. Campus de Beaulieu

4. CNRS-Université de Rennes 1

5. 35042 Rennes Cedex

6. Department of Theoretical Chemistry

7. Faculty of Chemistry

8. Jagiellonian University

9. 30-060 Krakow

10. Poland

11. Aix Marseille Université

12. Centrale Marseille

13. CNRS

14. iSm2 UMR 7313

15. Marseille

16. Department of Chemistry

17. San José State University

18. San José

19. USA

20. University of Durham

21. Durham

22. UK

23. University at Buffalo

24. State University of New York

25. Buffalo

Abstract

A new type of chiroptical switch based on a bis-helicenic terpyridine, changing conformation upon Zn binding, has been designed.

Funder

National Science Foundation

Agence Nationale de la Recherche

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01748G

Reference53 articles.

1. Transition metal-based chiroptical switches for nanoscale electronics and sensors

2. J. W. Canary and Z.Dai, Dynamic stereochemistry and chiroptical spectroscopy of metallo-organic compounds, in Comprehensive Chiroptical Spectroscopy, ed. N. Berova, R. W. Woody, P. Polavarapu and K. Nakanishi, John Wiley & Sons, Hoboken, NJ, USA, 2012, vol. 2

3. Coordination chemistry strategies for dynamic helicates: time-programmable chirality switching with labile and inert metal helicates

4. Chiroptical Switches: Applications in Sensing and Catalysis

5. Transfer of chirality from ligands to metal centers: recent examples

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