A metal–metal bond passing through the arene ligand: a theoretical study on inverse sandwiches X[Sc–C8H8–Sc]nX (X = F, Cl, Br; n = 1, 2)-Reference-Cited by-同舟云学术

A metal–metal bond passing through the arene ligand: a theoretical study on inverse sandwiches X[Sc–C8H8–Sc]nX (X = F, Cl, Br; n = 1, 2)

Published:2015 Issue:3 Volume:39 Page:1558-1562
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Liu Nan-nan¹²³⁴⁵,Ding Yi-hong⁶⁷⁸⁹⁵

Affiliation:

1. Chemistry Center

2. College of Food Engineering

3. Harbin University of Commerce

4. Harbin 150076

5. People's Republic of China

6. State Key Laboratory of Theoretical and Computational Chemistry

7. Institute of Theoretical Chemistry

8. Jilin University

9. Changchun 130023

Abstract

In X[Sc–C₈H₈–Sc]₂X (X = F–Br), Sc–Sc bonds between two [Sc–C₈H₈–Sc] units and the Sc–Sc bond through C₈H₈ form the uninterrupted Sc–Sc–Sc–Sc bond-chain.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C4NJ01832J

Reference20 articles.

1. The [Ga2(C5Me5)]+ Ion: Bipyramidal Double-Cone Structure and Weakly Coordinated, Monovalent Ga+

2. Stable “Inverse” Sandwich Complex with Unprecedented Organocalcium(I): Crystal Structures of [(thf)2Mg(Br)-C6H2-2,4,6-Ph3] and [(thf)3Ca{μ-C6H3-1,3,5-Ph3}Ca(thf)3]

3. A Formal High Oxidation State Inverse-Sandwich Diuranium Complex: A New Route to f-Block-Metal Bonds

4. Binding and Activation of Small Molecules by Three-Coordinate Cr(I)

5. Reduction of Titanium Supported by a σ-/π-Bonded Tripyrrole Ligand: Ligand C−N Bond Cleavage and Coordination of Olefin and Arene with an Inverse Sandwich Structure

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